Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II)
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چکیده
منابع مشابه
Tetraaquabis(pyridine-3-sulfonato-κN)nickel(II)
In the mol-ecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water mol-ecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octa-hedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π-π stacking between the pyridin...
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The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetra-hedral geometry. The Ag(I) ions are linked by μ(4)-5-bromo-pyridine-3-sulfonate ligands, forming a layer parallel to (100). The layers are further connected via C-H⋯Br hydrogen-bonding inter-ac...
متن کاملPoly[bis(μ7-3-sulfonato-l-alaninato)sodiumzinc]
The hydro-thermal reaction of Zn(CH(3)COO)(2), NaOH and l-cysteic acid produced the title compound, [Na(2)Zn(C(3)H(5)NO(5)S)(2)](n). The Zn(II) cation is situated on an inversion centre and is in a distorted octa-hedral environment, being chelated by two deprotoned l-cysteic acid ligands through two amino N atoms and two carb-oxy-lic O atoms, with the two axial positions occupied by two carb-ox...
متن کاملDiaquabis(4-oxo-1,4-dihydropyridine-3-sulfonato-κ2 O 3,O 4)zinc(II)
In the crystal structure of the title compound, [Zn(C(5)H(4)NO(4)S)(2)(H(2)O)(2)], the 4-oxo-1,4-dihydro-pyridine-3-sulfonate anion chelates to water-coordinated zinc centres through the carbonyl O atom and through one O atom of the sulfonate group. The Zn(II) atom lies on a center of inversion, and adjacent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, forming a three-dimensional ne...
متن کاملcatena-Poly[[diaquamanganese(II)]-di-μ-pyridine-3-sulfonato-κ2 N:O;κ2 O:N]
In the title polymeric complex, [Mn(C(5)H(4)NO(3)S)(2)(H(2)O)(2)](n), the Mn atom is located on a centre of inversion and is coordinated by two O atoms and two N atoms derived from four different pyridine-3-sulfonate (pySO(3)) ligands, and two O atoms derived from two water mol-ecules in a distorted trans-N(2)O(4) octa-hedral geometry. The metal atoms are bridged by the pySO(3) ligands to form ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808010076